The porous carbon material was synthesized from amphiphilic copolymer pluronic F127 as soft template and protonated chitosan solution as raw material, and the effects of pH value of solution and carbonization temperature on its pore structure, specific surface area and CO2 adsorption capacity were examined. The result showed that the highest specific surface area of porous carbon material reached 457 cm2/g, its highest nitrogen content was 7.60%, and its highest surface nitrogen content 8.45% in the form of pyridine. Its highest CO2 adsorption capacity reached 80.8 mg/g, and the adsorption efficiency was up to 0.274 mg/cm3.