Sulfuric acid and hydrochloric acid were used to research leaching process of Fe, Si, Zn, Pb in jarosite residue. The results showed that sulfuric acid leaching, leaching rate of Fe, Zn reached 80% under the optimum conditions of leaching temperature of 95℃, reaction time of 2 h, stirring speed of 300 r/min, concentration of sulfuric acid of 1.2 mol/L and mass ratio of liquid to solid of 100:5. Hydrochloric acid leaching, leaching rate of Fe, Zn, Pb reached to 83%, 89%, 99% under the optimum conditions of leaching temperature of 95℃, reaction time of 1.5 h, stirring speed 400 r/min, concentration of hydrochloric acid 2.8 mol/L and mass ratio of liquid to solid 100:5. Jarosite was used to get rid of Fe in leaching solution. Jarosite residue can be fixed treatment to finally obtain zn-rich Solution.