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  Controlled Synthesis of Nano-calcium Carbonate via Carbonization Method: A Review

  • CHENG Na ZHOU Mei-fang CHEN Peng-yu LI Chun-zhong JIANG Hai-bo ZHANG Ling
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  • Key Laboratory for Ultrafine Materials, Ministry of Education, School of Material Science and Engineering, East China University of Science and Technology, Shanghai 200237, China

Received date: 2016-08-30

  Revised date: 2016-10-14

  Online published: 2017-04-19

Abstract

With the development of the preparation technology of nano-CaCO3, the physicochemical properties and structure characteristics including particle size and its distribution, morphology and dispersity of CaCO3 have been well controlled, making this traditional inorganic material increasingly widely used in the field of coating, filler, paper making and polymer modification. Carbonization method is a kind of nanometer-CaCO3 preparation method with Ca(OH)2-H2O-CO2 as reaction system, which applied widely in the industrial preparation of nano-CaCO3. Focused on this method, firstly, several new reactors for the controlled synthesis procedure were introduced from the aspect of gas-liquid mass transfer enhancement, based on the traditional preparation methods of nano- CaCO3. Then, systematic analysis was taken to interpret the influence mechanism of four parameters: initial Ca(OH)2 concentration, CO2 partial pressure, the gas flow rate and temperature on the nucleation and crystal growth process of nano-CaCO3. The effects of several additives added during the carbonation process on the morphology and the dispersion of CaCO3 particles were introduced, and the mechanism of these additives was also described. Finally, some suggestions were put forward to settle the problems existing in the preparation of CaCO3.

Cite this article

CHENG Na ZHOU Mei-fang CHEN Peng-yu LI Chun-zhong JIANG Hai-bo ZHANG Ling .   Controlled Synthesis of Nano-calcium Carbonate via Carbonization Method: A Review[J]. The Chinese Journal of Process Engineering, 2017 , 17(2) : 412 -419 . DOI: 10.12034/j.issn.1009-606X.216287

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