Graphene was prepared by graphite oxide reduction method. Graphene was used to remove Cr(VI) from water as an absorbent. Effects of pH, temperature and graphene dosage on the adsorption capacity, adsorption thermodynamics and kinetics were discussed. The results showed that graphen was a good adsorbent of Cr(VI). The adsorption behavior was the favourable adsorption, conformed the Langmuir isotherm equation well. The adsorption process was spontaneous and endothermic process, it corresponded with pseudo-secong-order kinetic model, the activation energy was 88.62 kJ/mol.
Zhigong ZHENG Jinbei YANG Jinchao GUO Ronghui SHI
. Preparation of Graphene and its Application on the Adsorption of Cr(VI)[J]. The Chinese Journal of Process Engineering, 2017
, 17(5)
: 1085
-1090
.
DOI: 10.12034/j.issn.1009-606X.217104
[1] 张汉池,张继军,刘峰.铬的危害与防治[J].内蒙古石油化工,2004,01: 72-73
[2] 王谦,李延,孙平等.含铬废水处理技术及研究进展[J].环境科学与技术,2013,S2: 150-156
[3] 肖淑华,沈明,朱沛英等.水合肼还原氧化石墨烯的研究[J].材料开发与应用,2011,02: 45-50
[4] 袁小亚.石墨烯的制备研究进展[J].无机材料学报,2011,06: 561-570
[5] 杨旭宇,王贤保,李静等.氧化石墨烯的可控还原及结构表征[J].高等学校化学学报,2012,09: 1902-1907.
[6] 周锋,万欣,傅迎庆.氧化石墨还原法制备石墨烯及其吸附性能[J].深圳大学学报(理工版),2011,05:436-439.
[7] 邹正光,俞惠江,龙飞等.超声辅助Hummers法制备氧化石墨烯[J].无机化学学报,2011,09: 1753-1757
[8] 葛昊,田辉,李明霞,郝婷婷,宋赢,祁辅媛,范钦臻,宋溪明.反应条件对水合肼还原氧化石墨烯表面官能团还原效率的影响[J].辽宁大学学报(自然科学版),2014,03: 243-250
[9] 谢华林,杨华林.二苯碳酰二肼分光光度法测水中Cr6+[J].常德师范学院学报(自然科学版),2001,02:65-66
[10] 杨文武,张钧.水和废水中六价铬测定关键问题研究[J].环境工程,2010,28(3): 108-112
[11] Dakiky M,Khamis M,Manassra A.Standard methods for the examination of water and wastewater[J]. Adv. Environ. Res. 2002,4: 533-540
[12] Ho Y.S.,John Wase D.A.,Forster C.F.Batch nickel removal from aqueous solution by sphagnum moss peat[J].Water Research,1995,299(5):1327-1332
[13] 孟冠华,刘宝河,郑俊等.水杨酸修饰聚苯乙烯对Pb2 +和 Cu2 +的吸附[J].应用化学,2009,26( 2) : 219-223
[14] LIU Y,LIU Y.Biosorption isotherms,kinetics and thermodynamics[J].Separation and Purification Technology,2008,61( 3) : 229-242
[15] JAYCOCK M.J.,PARFITT G.D..Chemistry of Interfaces.Onichester,Ellis Horwood Co.Ltd.,1981: 12-13
[16] REDDAD Z.,GERENTE C.,ANDRES Y.,et al.Adsorption of several metalions onto a low-cost biosorbent:Kinetic and equilibrium studies[J].Environmental Science and Technology,2002,36( 9) : 2067-2073
[17] BARALSS,DASSN,RATHP.Hexavalent chromium removal from aqueous solution by adsorption on treated sawdust[J].Biochemical engineering journal,2006,31(3): 216-222