A method of mutual calculation between standard dissolved Gibbs free energy and differential dissolution enthalpy based on a model of dilute solution was proposed. The validation of the mutual calculation method was confirmed according to the standard dissolved Gibbs free energy and differential dissolution enthalpy in liquid iron and liquid nickel. The relationship between the standard dissolved Gibbs free energy and temperature was established based on differential dissolution enthalpy in liquid aluminum. The method of mutual calculation provided a basis for the thermodynamic calculation of chemical reaction in liquid metal in which the thermodynamic data such as standard dissolved Gibbs free energy was lacked.
Saijun XIAO Qian KOU Xiaohong FANG
. Mutual Calculation between Standard Dissolved Gibbs Free Energy and Differential Dissolution Enthalpy Based on a Model of Dilute Solution[J]. The Chinese Journal of Process Engineering, 2018
, 18(2)
: 417
-421
.
DOI: 10.12034/j.issn.1009-606X.217281
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