The methanol was adsorpted by water via the layered packing cross-flow rotating bed. The effects of operating parameters such as high gravitational factor (?), empty bed gas velocity (u), liquid spray density (q) and inlet methanol concentration on the overall volumetric gas-phase transfer coefficient (KGa) of methanol were explored. The results indicated that KGa increased with the increases of ?, u and q, but the inlet methanol concentrations had a negligible effect on the KGa of methanol. Under the conditions of ?=100, u=0.9 m/s, q=17.6 m3/(m2?h), the inlet concentration of methanol was 14000 mg/m3, the absorptivity of methanol on rate was 97%, the KGa values of methanol reached 27 s?1, which was 1.1~3.9 times of the countercurrent-flow rotating packed bed with blade packing, 2~7.7 times of the cross-flow rotating packed bed with blade packing. It showed that the device can effectively reduce the mass transfer resistance of gas film control. When the inlet concentration of methanol gas was stable, high u and low q, ???value had great influence on the KGa of methanol. The mass transfer efficiency in the process of methanol absorption was effectively enhanced. The empty bed gas velocity of this equipment reached 1 m/s, which was 3~12 times of the countercurrent-flow rotating packed bed with blade packing.
[1] 马超, 薛志钢, 李树文, 等. VOCs排放、污染以及控制对策[J]. 环境工程技术学报, 2012, 2(02): 103-109. .
MA Chao, XUE Zhigang, LI Shuwen, et al. VOCs Emission,Pollution and Control Measures[J]. Journal of Environmental Engineering Technology, 2012, 2(02): 103-109.
[2] 王治民, 孙建薇. 关于VOC废气处理技术的相关思考[J]. 能源与节能, 2014, (05): 97-99.
WANG Zhiming, SUN Jianwei. Relevant Thinking on the VOC Gas Treatment Technology[J]. Energy and Energy Conservation, 2014, (05): 97-99.
[3] KHAN F I, GHOSHAL A K. Removal of Volatile Organic Compounds from polluted air[J]. Journal of Loss Prevention in the Process Industries, 2000, 13(6): 527-545.
[4] 韩晓强,黄伟. VOC废气蓄热式热氧化处理方法[J]. 中国环保产业, 2012, (12): 43-45.
HAN Xiaoqiang, HUANG Wei. Regenerative Thermal Oxidation Treatment Process for VOC Gas[J]. China Environmental Protection Industry, 2012, (12): 43-45.
[5] 马文娇. 催化燃烧去除挥发性有机化合物的研究进展[J]. 科技视界, 2014, (32): 48-85.
MA Wenjiao. Research progress of catalytic combustion for removal of volatile organic compounds[J]. Science & Technology Vision, 2014, (32): 48-85.
[6] 徐伟, 张钰靓, 施延君, 等. 钙钛矿型催化剂去除VOC的性能研究[J]. 广东化工, 2011, 38(06): 273-274.
XU Wei, ZHANG Yuliang, SHI Yanjun, et al. Preparation of Supported Perovskite Catalysts and Its Performance for the Catalytic Combustion of VOCs[J]. Guangdong Chemical Industry, 2011, 38(06): 273-274.
[7] HEYMES F, MANNO-DEMOUSTIER P, CHARBIT F, et al. A new efficient absorption liquid to treat exhaust air loaded with toluene[J]. Chemical Engineering Journal, 2006, 115(3): 225-231.
[8] LALANNE F, MALHAUTIER L, ROUX JC, FANLO JL. Absorption of a mixture of volatile organic compounds (VOCs) in aqueous solutions of soluble cutting oil[J]. Bioresource Technology, 2008, 99(6): 1699-1707.
[9] JI W, HILALY A, SIKDAR S K, et al. Optimization of multicomponent pervaporation for removal of volatile organic compounds from water[J]. Journal of Membrane Science, 1994, 97(1): 1-19.
[10] BYEON J H, PARK J H, YOON K Y, et al. Removal of volatile organic compounds by spark generated carbon aerosol particles[J]. Carbon, 2006, 44(10): 2106-2108.
[11] DAUBERT I, LAFFORGUE C C, FONADE C. Feasibility study of a compact process for biological treatment of highlysoluble VOCs polluted gaseous effluent[J]. Biotechnology Progress, 2001, 17(6):1084-1092.
[12] RAMSHAW C, MALLINSON R H. Mass transfer process[J]. 1981.
[13] 宋剑飞. 活性炭吸附VOCs及其构效关系研究[D]. 中南大学, 2014.
SONG Jianfei. Studies on the adsorpition of VOCS by activated carbons and the structure-function relationship[D]. Central South University, 2014.
[14] 祁贵生, 刘有智, 王焕, 等. 不同填料错流旋转填料床气液传质特性研究[J]. 化学工程, 2014, 42(05): 18-22.
QI Guisheng, LIU Youzhi, WANG Huan, et al. Gas-liquid mass-transfer characteristic in cross-flow rotating packed bed with different packings[J]. Chemical Engineering, 2014, 42(05): 18-22.
[15] 祁贵生,焦纬洲,刘有智,等. 新型填料结构旋转床传质特性 [J]. 化学反应工程与工艺, 2009, 25(2): 109-115.
QI Guisheng, JIAO Weizhou, LIU Youzhi, et al. Mass Transfer Characteristics of a Rotating Packed Bed with New Type Packings [J]. Chemical Reaction Engineering and Technology, 2009, 25(2): 109-115.
[16] 康荣灿,刘有智,焦纬洲,等. 填料结构对错流旋转填料床传质性能的影响 [J]. 青岛科技大学学报, 2007, 28(5): 406-409.
KANG Rongcan, LIU Youzhi, JIAO Weizhou, et al. Effect of Different Packing Structure on Mass Transfer in a Cross-flow Rotating Packed Bed [J]. Journal of Qingdao University of Science and Technology, 2007, 28(5): 406-409.
[17] AND Y S C, LIU H S. Absorption of VOCs in a Rotating Packed Bed[J]. Industrial & Engineering Chemistry Research, 2008, 41(6):1583-1588.
[18] LIN C C, LIN Y C. Mass transfer performance of a rotating packed bed equipped with blade packings in removing methanol and 1-butanol from gaseous streams[J]. Chemical Engineering & Processing Process Intensification, 2012, 53(3):76-81.
[19] LIN C C, LIN Y C, CHEN S C, et al. Evaluation of a rotating packed bed equipped with blade packings for methanol and 1-butanol removal[J]. Journal of Industrial & Engineering Chemistry, 2010, 16(6):1033-1039.
[20] SUNG W D, CHEN Y S. Characteristics of a rotating packed bed equipped with blade packings and baffles[J]. Separation & Purification Technology, 2012, 93(93): 52-58.
[21] RAO D P, A. BHOWAL ? A, Goswami P S. Process Intensification in Rotating Packed Beds (HIGEE):An Appraisal[J]. Industrial & Engineering Chemistry Research, 2004, 43(4): 1150-1162.
[22] ZHENG C, GUO K, YUANDING FENG A, et al. Pressure Drop of Centripetal Gas Flow through Rotating Beds[J]. Industrial & Engineering Chemistry Research, 2000, 39(3):829-834.
[23] HSU L J, LIN C C. Binary VOCs absorption in a rotating packed bed with blade packings[J]. Journal of Environmental Management, 2012, 98(98): 175-182.
[24] 张近. 塔填料研究进展[J]. 化工进展,1989, (06): 9-19.
ZHANG Jin. Research progress of tower packing[J]. Chemical Industry and Engineering Progress,1989, (06): 9-19.
[25] LIN C C, CHIEN K S. Mass-transfer performance of rotating packed beds equipped with blade packings in VOCs absorption into water[J]. Separation & Purification Technology, 2008, 63(1):138-144.
[26] RAFSON H J. Odor and VOC control handbook[J]. 1998.
[27] 刘有智. 超重力化工过程与技术[M]. 国防工业出版社, 2009.2-3.
LIU Youzhi. Chemical Engineering Process and Technology in High Gravity [M]. Beijing: National Defence Industry Press, 2009, 2-3.
[28] SHEN K P, WEI T Y, LIU W T, et al. Removal of VOCs from Gaseous Streams in a High-Voidage Rotating Packed Bed[J]. Journal of Chemical Engineering of Japan, 2004, 37(12): 1471-1477.
[29] CHEN Y S, HSU Y C, LIN C C, et al. Volatile organic compounds absorption in a cross-flow rotating packed bed.[J]. Environmental Science & Technology, 2008, 42(7):2631-6.