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Research progress on desulfurization technology for blast furnace gas

  • WANG Xin-Dong ,
  • ZHU Ting-Yu ,
  • LI Yu-Ran
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  • 1. HBIS Group Co. Ltd., Shijiazhuang, Hebei 050023, China 2. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received date: 2022-09-12

  Revised date: 2022-11-09

  Online published: 2023-07-28

Abstract

The desulfurization technology for blast furnace gas as a source of emission reduction technology is of great significance to promoting ultra-low emission for the whole process in the iron-steel industry. The sulfur-containing components in the blast furnace gas are mainly organic sulfur, coexisting with other complex components. This work discusses the emission limits of sulfur-containing components in various occurrence forms (SO2, H2S, and S), and analyzes their transformation relationship through the mass balance of sulfur. The bottleneck of desulfurization technology for blast furnace gas is to remove the carbonyl sulfur (COS). The aluminum-based catalyst and carbon-based catalyst used for COS catalytic hydrolysis are analyzed in detail, in which γ-Al2O3 is both a carrier and an active component, and activated carbon has the functions of catalyst and adsorbent. The effect mechanism of the complex components O2, and Cl- on the deactivation of hydrolysis catalyst is further elucidated due to the formation of deposition products. For the gaseous H2S formed after the COS hydrolysis, the two kinds of wet removal technology, mainly including the chemical absorption method and catalytic oxidation method, are compared in the reaction mechanism, desulfurizer and product. The difference among the zinc oxide, iron oxide, and activated carbon adsorbent used in the dry removal technology is also concretely elaborated in the reaction mechanism, sulfur capacity, and temperature adaptability. In view of the integrated adsorption of organic sulfur and inorganic sulfur, molecular sieve adsorbent is briefly described in the selective adsorption principle and regeneration process. The "hydrolysis+wet", "hydrolysis+dry", and integrated removal processes have been explored and applied currently, which are preliminarily evaluated. Finally, it is pointed out that the research and development of desulfurization technology focus on how to improve the activity of the hydrolysis catalyst and reduce the influence of complex components in blast furnace gas on catalyst activity and improve the applicability of the technology.

Cite this article

WANG Xin-Dong , ZHU Ting-Yu , LI Yu-Ran . Research progress on desulfurization technology for blast furnace gas[J]. The Chinese Journal of Process Engineering, 2023 , 23(7) : 1003 -1012 . DOI: 10.12034/j.issn.1009-606X.222334

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