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神木烟煤热解产物分布及主要元素的迁移规律

  • 石振 成帅 陈兆辉 张建岭 高士秋 许光文
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  • 1. 中国科学院过程工程研究所多相复杂系统国家重点实验室
    2. 中国科学院过程工程研究所多相反应重点实验室

收稿日期: 2016-04-11

  修回日期: 2016-05-10

  网络出版日期: 2016-10-14

Distribution of Products and Migration of Main Elements during Pyrolysis of Shenmu Bituminous Coal

  • SHI Zhen CHENG Shuai CHEN Zhao-hui ZHANG Jian-ling GAO Shi-qiu XU Guang-wen
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  • Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences

Received date: 2016-04-11

  Revised date: 2016-05-10

  Online published: 2016-10-14

摘要

在石英管固定床反应器中对神木烟煤进行热解实验,研究了热解温度对煤热解产物分布和C, H, O, N, S元素在热解产物中分配的影响. 结果表明,在500?900℃范围内,随热解温度升高,半焦产率下降,气体产率增大,焦油产率先增大后降低,600℃时达最大值9.2%(ω);半焦中C, H, O和N元素迁入量下降,S元素迁入量先降低后略有增大,在700℃时达最小值67.0%;热解气中C, H, O元素迁入量增大,N元素和S元素迁入量先增大后减小,分别在800和600℃时达最大值28.8%和27.9%;焦油中C, H, O元素迁入量先增大后降低,均在600℃时分别达最大值9.3%, 14.0%和7.2%,N元素和S元素迁入量缓慢增加;热解水中H和O元素迁入量先增大后略有降低,在700℃时分别达最大值14.5%和48.5%.

本文引用格式

石振 成帅 陈兆辉 张建岭 高士秋 许光文 . 神木烟煤热解产物分布及主要元素的迁移规律[J]. 过程工程学报, 2016 , 16(5) : 802 -811 . DOI: 10.12034/j.issn.1009-606X.216179

Abstract

The effect of pyrolysis temperature on distribution of products and migration of main elements (C, H, O, N, S) during pyrolysis of Shenmu bituminous coal was investigated in a fixed-bed quartz reactor. The results showed that with the pyrolysis temperature increasing from 500℃ to 900℃, the char yield decreased and the gas yield increased continuously, while the tar yield increased to a maximum of 9.2%(?) at 600℃ and then declined. When the pyrolysis temperature increased, the transfer ratios of C, H, O and N in the char decreased, and the transfer ratio of S in the char decreased firstly and then increased with the minimum ratio of 67.0% at 700℃. With the increase of temperature, the transfer ratios of C, H and O in the gas increased, and the transfer ratios of N and S in the gas increased firstly and then decreased at 800 and 600℃ with the maximum values of 28.8% and 27.9%, respectively. The transfer ratios of C, H and O in the tar increased firstly to the maximum values of 9.3%, 14.0% and 7.2% at 600℃, respectively, and then decreased, while the transfer ratios of N and S slightly increased with the pyrolysis temperature increasing. The transfer ratios of H and O in the water increased firstly to the maximum values of 14.5% and 48.5% at 700℃, respectively, and then decreased slightly with pyrolysis temperature increasing.
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