4,4&rsquo;-二羟基二苯砜在乙酸乙酯-苯混合溶剂中溶解度测定

谢永 赵国庆 史洪伟 王红艳 汪丽

doi:10.12034/j.issn.1009-606X.216278

过程工程学报 >

2017 , Vol. 17 >Issue 2: 371 - 374

DOI: https://doi.org/10.12034/j.issn.1009-606X.216278

过程与工艺

4,4’-二羟基二苯砜在乙酸乙酯-苯混合溶剂中溶解度测定

谢永赵国庆史洪伟王红艳汪丽

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1. 宿州学院化学化工学院，安徽宿州 234000；
2. 中南大学化学化工学院，湖南长沙 410083；
3. 宿州学院精细化工产品开发研究所，安徽宿州 234000

收稿日期: 2016-08-25

修回日期: 2016-10-23

网络出版日期: 2017-04-19

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Measurement for 4,4'-Dihydroxydiphenylsulfone Solubility in Ethyl acetate+Benzene Mixture Solvents

XIE Yong ZHAO Guo-qing SHI Hong-wei WANG Hong-yan WANG Li

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1. School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Anhui 234000, China;
2. School of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan 410083, China;
3. Fine Chemical Product Development Research Institute, Suzhou University, Suzhou, Anhui 234000, China

Received date: 2016-08-25

Revised date: 2016-10-23

Online published: 2017-04-19

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摘要

采用激光辅助质量法测定了283.15~333.15 K下4,4?-二羟基二苯砜在乙酸乙酯?苯混合溶液中的溶解度. 结果表明，4,4′-二羟基二苯砜的溶解度随混合溶液中苯摩尔分数增加而下降，随温度升高显著增加. 用改进的Apelblat经验方程和??h方程关联溶解度数据，改进的Apelblat经验方程的均方根偏差为19.86?10?3，优于??h方程的均方根偏差39.24?10?3.

关键词： 4,4′-二羟基二苯砜; 溶解度; 混合溶剂; 质量法

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谢永赵国庆史洪伟王红艳汪丽 . 4,4’-二羟基二苯砜在乙酸乙酯-苯混合溶剂中溶解度测定[J]. 过程工程学报, 2017 , 17(2) : 371 -374 . DOI: 10.12034/j.issn.1009-606X.216278

Abstract

Solubility of 4,4?-dihydroxydiphenylsulfone in ethyl acetate?benzene mixture solvents was measured using the ways of laser-assisted quality system of 283.15~333.15 K. The results showed that solubility of 4,4'-dihydroxydiphenylsulfone in the mixture solvent decrease with the increase of benzene mole fraction in solvents and increase significantly with the rise of temperature. Modified Apelblat equation and ??h equation were used in data regression and the average root-mean-square deviation are 19.86?10?3, 39.24?10?3 respectively, modified Apelblat equation provides better fitting result.

Key words： 4,4?-dihydroxydiphenylsulfone; solubility; mixture solvents; quality laws

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