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玉米秸秆与煤流化床的共气化特性

  • 曾曦 敖先权 曹阳 杨爱江
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  • 1. 贵州大学资源与环境工程学院
    2. 贵州省贵阳市贵州大学蔡家关校区化学工程学院
    3. 贵州大学 化学与化工学院

收稿日期: 2016-09-25

  修回日期: 2016-11-18

  网络出版日期: 2017-06-14

基金资助

贵州省科技厅重大应用基础研究项目;贵州省科技厅重大专项资助项目;教育部春晖计划资助项目

Effect of Air Vapor on Co-gasification of Corn Stalks and Coal in Fluidized-bed

  • Xi ZENG Xianquan AO Yang CAO Aijiang YANG
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  • 1. School of Resources and Environment Engineering, Guizhou University, Guiyang, Guizhou 550025, China;
    2. School of Chemistry and Chemical Engineering, Guizhou University, Guiyang, Guizhou 550025, China;
    3. Institute of Environmental Engineerting Planing and Design, Guizhou University, Guiyang, Guizhou 550025, China

Received date: 2016-09-25

  Revised date: 2016-11-18

  Online published: 2017-06-14

摘要

以玉米秸秆与无烟煤为原料,在循环流化床中进行空气-水蒸汽气化试验,采用预热装置将气化剂(空气、水蒸汽)由常温加热至500 ℃,研究了不同气化温度、气化剂类型及生物质掺混比例对气化燃气组分和热值、气化效率及碳转化率等评价指标的影响。结果表明:提高气化温度能增大碳转化率及气化效率,在800~1000℃范围内,无烟煤单独气化950 ℃时气化效率最高,掺混比(m玉米秸秆:m煤)20%的混合试样850 ℃时气化效率最高;选择空气-水蒸汽气化剂时,H2体积分数由1.80%增加到15.53%;随着玉米秸秆掺混比增加,促进了CO的生成,抑制了CO2的生成,但掺混比例大于40%时会降低燃气热值及碳转化率。使用空气作气化剂,掺混比20%时燃气热值最高,选择空气-水蒸汽作气化剂时,掺混比40%时燃气热值最高。

本文引用格式

曾曦 敖先权 曹阳 杨爱江 . 玉米秸秆与煤流化床的共气化特性[J]. 过程工程学报, 2017 , 17(3) : 551 -557 . DOI: 10.12034/j.issn.1009-606X.216309

Abstract

In order to study the influence of gasification temperature, gasification agents and blending ratios on gas component, low heat value (LHV), gasification efficiency and carbon conversion rate during co-gasification in a circulating fluidized bed, experimental tests were carried out with air vapor of room temperature heated to 500 ℃. Results show that the rise in gasification temperature can promote the carbon conversion rate and the gasification efficiency. The highest gasification efficiency of anthracite gasification alone is at 950 ℃ between the range of 800~1000 ℃, and the highest gasification efficiency of corn stalks sample of 20% blending ratio is at 850 ℃. With air vapor being the gasification agents, H2 increased from 1.80% to 15.53%. The addition of corn stalk promoted the generation of CO while inhibited the generation of CO2. But LHV, carbon conversion rate and gasification efficiency decreased when blending ratio exceeds 40%. With air being the gasification agent, the highest LHV appeared at 20% blending ratio, and with air vapor as the gasification agent, the highest LHV appeared when the blending ratio was 40%.
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