改性钢渣代炭黑环保型丁苯橡胶的制备及其性能

张浩 杨刚 龙红明 唐刚 刘秀玉

doi:10.12034/j.issn.1009-606X.217165

过程工程学报 >

2017 , Vol. 17 >Issue 6: 1299 - 1303

DOI: https://doi.org/10.12034/j.issn.1009-606X.217165

材料工程

改性钢渣代炭黑环保型丁苯橡胶的制备及其性能

张浩杨刚龙红明唐刚刘秀玉

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1. 安徽工业大学建筑工程学院，安徽马鞍山 243032；2. 冶金减排与资源综合利用教育部重点实验室(安徽工业大学)，安徽马鞍山 243002; 3. 中冶宝钢技术服务有限公司，上海 200941；4. 钢铁冶金新技术国家重点实验室(北京科技大学)，北京 100083; 5. 安徽工业大学冶金工程学院，安徽马鞍山 243032

收稿日期: 2017-03-09

修回日期: 2017-04-04

网络出版日期: 2017-12-05

基金资助

冶金减排与资源综合利用教育部重点实验室(安徽工业大学)资助项目;钢铁冶金新技术国家重点实验室（北京科技大学）资助项目

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Preparation of Environmentally Friendly Styrene Butadiene Rubber with Modified Steel Slag Instead of Carbon Black and Their Properties

Hao ZHANG Gang YANG Hongming LONG Gang TANG Xiuyu LIU

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1. School of Civil Engineering and Architecture, Anhui University of Technology, Ma?anshan, Anhui 243032, China; 2. Key Lab. Metall. Emission Redut. Resourc. Recycl. (Anhui Univ. Technol.), Ministry of Education, Ma?anshan, Anhui 243002, China; 3. MCC Baosteel Technology Services Co., Ltd., Shanghai 200941, China; 4. State Key Laboratory of Advanced Metallurgy (University of Science and Technology of Beijing), Beijing 100083, China; 5. School of Metallurgical Engineering, Anhui University of Technology, Ma?anshan, Anhui 243032, China

Received date: 2017-03-09

Revised date: 2017-04-04

Online published: 2017-12-05

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摘要

用磷酸和钢渣制备改性钢渣，以改性钢渣取代部分炭黑与丁苯橡胶复合，制备改性钢渣代炭黑环保型丁苯橡胶，研究了磷酸/钢渣质量比、改性钢渣/炭黑质量比和促进剂/硫磺质量比对所制样品力学性能的影响. 结果表明，当磷酸/钢渣质量比为10:250时，改性钢渣具有最优的孔结构，比表面积为15.093 m2/g，孔体积为0.0868 mL/g，平均孔径为24.87 nm；当改性钢渣/炭黑质量比为260:250、促进剂/硫磺质量比为10:15时，丁苯橡胶的力学和经济综合性能最佳，拉伸强度为23.7 MPa，邵尔A硬度为67.9，撕裂强度为41.2 kN/m.

关键词： 改性钢渣; 炭黑; 丁苯橡胶; 环保; 力学性能

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张浩杨刚龙红明唐刚刘秀玉 . 改性钢渣代炭黑环保型丁苯橡胶的制备及其性能[J]. 过程工程学报, 2017 , 17(6) : 1299 -1303 . DOI: 10.12034/j.issn.1009-606X.217165

Abstract

Phosphoric acid and steel slag were used to prepare modified steel slag, then, environmentally friendly styrene butadiene rubber were prepared by synthesizing styrene butadiene and carbon black partially substituted by modified steel slag. The effects of ratios of phosphoric acid/steel slag, modified steel slag/carbon black and accelerator/sulfur on the mechanical properties of prepared samples were studied, respectively. The results showed that when the mass ratio of phosphoric acid/steel slag was 10:250, modified steel slag showed the optimal pore structure, the specific surface area, pore volume and average pore diameter were 15.093 m2/g, 0.0868 mL/g and 24.87 nm accordingly. With the mass ratios of modified steel slag/carbon black and accelerator/sulfur as 260:250 and 10:15, the prepared sample presents the best comprehensive performance in terms of mechanics and economy, tensile strength 23.7 MPa, Shore A hardness 67.9 and tear strength 41.2 kN/m.

Key words： modified steel slag; carbon black; styrene butadiene rubber; environmentally friendly; mechanical property

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