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HPP–Na2SO3–H2O双水相体系相平衡数据测定及关联

  • 郑争志 刘雅婷 崔鹏
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  • 1. 合肥工业大学化学与化工学院,可控化学与材料化工安徽省重点实验室,安徽 合肥 230009;2. 安徽大学化学化工学院,安徽 合肥 230601

收稿日期: 2017-08-25

  修回日期: 2017-11-13

  网络出版日期: 2018-06-06

基金资助

安徽省重点科技攻关项目

Measurement data and correlation of liquid-liquid equilibria for aqueous two-phase systems of HPP-Na2SO3-H2O

  • Zhengzhi ZHENG Yating LIU Peng CUI
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  • 1. School of Chemistry & Chemical Engineering, Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, Hefei University of Technology, Hefei, Anhui 230009, China; 2. School of Chemistry & Chemical Engineering, Anhui University, Hefei, Anhui 230601, China

Received date: 2017-08-25

  Revised date: 2017-11-13

  Online published: 2018-06-06

摘要

采用浊点法和相组分分析法测定了不同温度下N,N?-二(2-羟丙基)哌嗪(HPP)–Na2SO3–H2O双水相体系的双节线和相平衡数据,并分别采用多项式、经验方程、有效体积排除法模型和NRTL模型对双节线数据和相平衡数据进行了关联. 结果表明,经验方程对双节线数据关联的吻合度高于多项式方程和有效体积排除法模型,且NRTL模型能很好关联该双水相相平衡数据. 除忽略可填充体积分数f213的有效体积排除法模型外,其余方程和模型的关联参数均能满足实际计算和工程应用.

本文引用格式

郑争志 刘雅婷 崔鹏 . HPP–Na2SO3–H2O双水相体系相平衡数据测定及关联[J]. 过程工程学报, 2018 , 18(3) : 557 -562 . DOI: 10.12034/j.issn.1009-606X.217312

Abstract

The binodal and liquid?liquid equilibrium data of the 1,4-bis-(2-hydroxypropyl)-piperazine (HPP)–Na2SO3–H2O system at different temperatures were determined by cloud point method and phase component analysis method respectively. The binodal data were fitted by polynomial equation, empirical equations and effective excluded volume theory models respectively and the liquid?liquid equilibrium data were fitted by NRTL model. The results showed that empirical equations can provide better correlations for the binodal data than the polynomial equation and the effective excluded volume theory ones, and the NRTL model was suitable for the liquid?liquid equilibrium relationship of HPP–Na2SO3–H2O. Except the effective excluded volume theory model neglecting volume fraction f213, the parameters of equations and models were consistent with the actual calculation and engineering application requirements.

参考文献

[1] Santesson S, Ramirez I B R, Viberg P, et al. Affinity two-phase partitioning in acoustically levitated drops [J]. Analytical Chemistry, 2004, 76(2): 303?308.
[2] Xu K, Wang Y, Huang Y, et al. A green deep eutectic solvent-based aqueous two-phase system for protein extracting [J]. Analytica Chimica Acta, 2015, 864(3): 9–20.
[3] Everberg H, Clough J, Henderson P, et al. Isolation of escherichia coli inner membranes by metal affinity two-phase partitioning [J]. Journal of Chromatography A, 2006, 1118(2): 244?252.
[4] Chen Y, Deng Y, Meng Y, et al. Partitioning equilibria and thermodynamics of gallium, indium, and thallium in aqueous two-phase systems [J]. Journal of Chemical and Engineering Data, 2015, 60(5): 1464?1468.
[5] Zhang Y, Sun T, HouU Q, et al. A green method for extracting molybdenum (VI) from aqueous solution with aqueous two-phase system without any extractant [J]. Separation and Purification Technology, 2016, 169(1): 151-157.
[6] Burcu T, Berna K, Leman T. Partitioning and purification of menadione induced NAD(P)H oxidase from Phanerochaete chrysosporium in aqueous two-phase systems [J]. Separation and Purification Technology, 2016, 163(2): 275–281.
[7] Carlos E A P, Paulo V F D, Franclsco C S J, et al. Recovery and concentration of ortho-phenylphenol from biodesulfurization of 4-methyl dibenzothiophene by aqueous two-phase flotation [J]. Separation and Purification Technology, 2017, 176(4): 306–312.
[8] Cui P, Wang T, Chen Y, et al. Density, viscosity, and surface tension of aqueous solution of 1, 4-bis- (2-hydroxypropyl) -piperazine sulfate [J]. Journal of Chemical and Engineering Data, 2013, 58(12): 3327–3331.
[9] Barbosa A A, Bonomo R C F, Martins C V, et al. Equilibrium data and physical properties of aqueous two phase systems formed by PEG (1500 and 4000) g·mol?1+ sodium sulfate + water at different temperatures and pH 2 [J]. Journal of Chemical and Engineering Data, 2016, 61, 3?11.
[10] Bonifacio P L, Aguiar C D, Alvarenga B G, et al. Phase diagrams for liquid?liquid equilibrium of aqueous two-phase system containing poly(ethylene glycol) (4000, 6000, or 10 000 g mol?1 + sodium hydrogen sulfite + Water) at different temperatures [J]. Journal of Chemical and Engineering Data, 2016, 61(6): 2062?2070.
[11] Alvarenga B G, Virtuoso L S, Lemes N H T, et al. Measurement and correlation of the phase equilibrium of aqueous two-phase systems composed of polyethylene(glycol) 1500 or 4000 + sodium sulfite + water at different temperatures[J]. Journal of Chemical and Engineering Data, 2014, 59 (2) :382–390.
[12] Virtuoso L S, Vello K A S F, Oliveira A A D, et al. Measurement and modeling of phase equilibrium in aqueous two phase systems: L35 + sodium citrate + water, L35 sodium tartrate + water, and L35 + sodium hydrogen sulfite + water at different temperatures[J]. Journal of Chemical and Engineering Data, 2012, 57 (2) :462–468.
[13] 国家环境保护总局. 固定污染源排气中二氧化硫的测定-碘量法: HJ/T 56-2000 [S]. 北京: 中国标准出版社, 2000.
State Environmental Protection Administration. Determination of Sulphur dioxide from exhausted gas of stationary source—Lodine titration method: HJ/T 56-2000 [S]. Beijing: Standards Press of China, 2000.
[14] 程浩. 无机离子对HPP-SO2吸收体系的影响与分离研究[D]. 合肥:合肥工业大学, 2016.
Cheng H. The relationship between the weight of a plant part and total weight as affected by plant density[D]. Hefei: Hefei University of Technology, 2016.
[15] Merechuk J C, Andrews B A, Asenjo J A. Aqueous two-phase systems for protein separation studies on phase inversion [J]. J Chromatogr B, 1998, 711(1-2): 285-293.
[16] Santos P L, Santos L N S, Ventura S P M, et al. Recovery of capsaicin from Capsicum frutescens by applying aqueous two-phase systems based on acetonitrile and cholinium-based ionic liquids[J]. Chemical Engineering Research and Design, 2016, 112(8): 103-112.
[17] Morandeiral L, Deive F J, Sanroman M A, et al. Aqueous two-phase systems containing imidazolium ionic liquids and a Tween surfactant[J]. J. Chem. Thermodynamics, 2017, 105: 209-216.
[18] Milosevic M, Staal K J J, Schuur B, et al. Experimental data and thermodynamic modeling of ternary aqueous biphasic systems of EO/PO polymers–Na2SO4–H2O [J]. Fluid Phase Equilibria, 2014, 366(2): 45-56.
[19] Guan Y, Lillry T H, Treery T E. A New excluded volume theory and its application to the coexistence curves of aqueous polymer two-phase systems [J]. Macromolecules 1993, 26(15): 3971-3979.
[20] Regupathi I, Monteiro S L. 1-Hexyl-3-Methylimidazolium chloride-potassium carbonate aqueous two phase system: equilibrium characteristics and BSA partitioning behavior[J]. Journal of Dispersion Science and Technology, 2014, 35 (3) :31-35.
[21] Taha M, Teng H L, Lee M J. Separation of tetrahydrofuran, 1,3-dioxolane, or 1,4-dioxane from their aqueous solutions using EPPS buffer at 298.15 K[J]. Separation and Purification Technology, 2013, 105 (5) :33-40.
[22] Lu Y, Cong B, Han J, et al. Measurement and correlation of phase equilibria in aqueous two-phase systems containing polyoxyethylenecetyl ether and potassium salt at different temperatures[J]. Journal of Chemical and Engineering Data, 2015, 60, 1193?1201.
[23] Othmer D F, Tobias P E. Tie-line correlation[J]. Industrial and Engineering Chemistry, 1942, 34(6): 693?696.
[24] Iyyaswami R, Shanon L M. 1-Hexyl-3-Methylimidazolium chloride-potassium carbonate aqueous two phase system: equilibrium characteristics and BSA partitioning behavior[J]. Journal of Dispersion Science and Technology, 35(3):418–427, 2014.
[25] 许文. 高等化工热力学[M]. 天津: 天津大学出版社, 2004: 183-184.
Xu W. Advanced Chemical Engineering Thermodynamics [M]. Tianjin: Tianjin University Press, 2004: 183-184.
[26] Renon H, Prausnitz J.M. Local compositions in thermodynamic excess function for liquid mixtures [J]. Aiche Journal, 1968, 14(1): 135-144.
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