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材料工程

金属基有机硅树脂涂层复合材料的导热性能

  • 王赶强 王景甫 张新欣 张涛
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  • 1. 北京工业大学传热强化与过程节能教育部重点实验室,北京 100124
    2. 北京工业大学传热与能源利用北京市重点实验室,北京 100124
    3. 胜利油田胜利动力机械集团有限公司,山东 东营 257032

收稿日期: 2017-09-21

  修回日期: 2017-12-22

  网络出版日期: 2018-08-15

基金资助

国家重点基础研究发展规划(973)

Thermal conductivity property of metal based silicone resin coating composite

  • Ganqiang WANG Jingfu WANG Xinxin ZHANG Tao ZHANG
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  • 1. Key Laboratory of Enhanced Heat Transfer and Energy Conservation, Ministry of Education, Beijing University of Technology,
    Beijing 100124, China
    2. Key Laboratory of Heat Transfer and Energy Conversion, Beijing Municipality,Beijing University of Technology, Beijing 100124,
    China
    3. Shengli Oilfield Victory Power Machinery Group Co., Ltd., Dongying, Shandong 257032, China

Received date: 2017-09-21

  Revised date: 2017-12-22

  Online published: 2018-08-15

摘要

以锌粉为导热填充剂对环氧有机硅树脂进行改性,考察了改性环氧有机硅树脂涂层干膜中锌粉含量对涂层导热系数的影响,分析了涂层厚度对碳钢基材导热性能的影响. 结果表明,环氧有机硅树脂涂层的导热系数约为0.19 W/(m?K),其耐温能力在200℃以上,可保证涂层在中低温烟气余热回收换热器表层长期工作而不发生任何热反应;添加锌粉可改善环氧改性有机硅涂层的导热性能,涂层干膜锌粉25wt%时,涂层材料导热系数达0.35 W/(m?K),较未添加锌粉时增大了84%. 复合材料的导热系数随涂层厚度增加而下降,无涂层的碳钢导热系数为47.59 W/(m?K),涂层厚度为200 ?m时,导热系数降至34.33 W/(m?K).

本文引用格式

王赶强 王景甫 张新欣 张涛 . 金属基有机硅树脂涂层复合材料的导热性能[J]. 过程工程学报, 2018 , 18(4) : 785 -791 . DOI: 10.12034/j.issn.1009-606X.217341

Abstract

The epoxy silicone resin was modified using zinc powder as heat conducting filler. Effect of zinc powder mass fraction on the thermal conductivity of modified epoxy organosilicon dry film coating was researched and the effect of coating thickness on the thermal conductivity of carbon steel was analyzed. The results showed that The thermal conductivity of silicone coating is around 0.19 W/(m?K), and heat-resistant temperature is above 200℃. Thus, the coating can ensure the long-term coating work in the low temperature flue gas waste heat recovery heat exchanger surface without any thermal reaction. Addition of zinc powder can improve the thermal conductivity of modified epoxy organosilicon coating. As the zinc powder content is 25wt%, the thermal conductivity of the coating material can increase 84% to 0.35 W/(m?K). Generally, with the increase of coating thickness, the thermal conductivity of metal matrix composite silicone coating decreases. The thermal conductivity of uncoated carbon steel was 47.59 W/(m?K), and the thermal conductivity of the coated carbon steel decreased to 34.33 W/(m?K) when the coating thickness was 200 μm.

参考文献

[1]车得福, 庄正宁, 李军, 等.锅炉[M]. 西安: 西安交通大学出版社, 2010. 52—53.
[2]郑永新, 赵恒谊, 叶远璋, 等.冷凝式燃气热水器换热器低温段防腐试验研究[J].煤气与热力, 2006, 27(7):35-41
[3]李旭日, 李瑞生.锌粉对环氧树脂防腐涂层改性的研究[J].辽宁化工, 2017, 41(9):882-884
[4]刘广娟,左禹,赵景茂.环氧改性有机硅涂料耐热耐蚀性研究[J].腐蚀与防腐, 2004, 25(6):238-241
[5]Mathivanan L, Radhakrishna S.Heat-resistant anti-corrosive paint from epoxy-silicone vehicles[J].Anti-Corrosion Methods and Materials, 1997, 44(6):400-406
[6]赵惠斌.环氧改性有机硅树脂--防腐涂料的最佳解决方案[J].上海涂料, 2013, 51(4):53-55
[7]余锡宾, 王华林.丙烯酸树脂与聚硅氧烷接枝改性的研究[J].高分子材料科学与工程, 1998, 14(2):129-131
[8]wanxun He, wenkang Shi, ping Cai, Ailun Ye.Applications of acrylate-based polymer and silicone resin on LPFG-based devices[J].Optical Materials, 2003, 21(2):507-510
[9]Hamid Javaherian Naghash, Shadpour Mallakpour, Neda Kayhan.Synthesis and characterization of silicone modified acrylic resin and its uses in the emulsion paints[J].Iranian Polymer, 2005, 14(3):211-222
[10]LI Jing, LIANG Ju, LIU Yeming.High-Thermal Conductive Coating Used on Metal Heat Exchanger[J].Chinese Journal of Chemical Engineering, 2014, 22(5):596-601
[11]陈跃, 冯显富, 黄鑫.广东石化换热器有机涂层防腐技术应用策略[J].全面腐蚀控制, 2013, 27(12):40-43
[12]余存烨.对石化换热器涂镀层厚度过薄的质疑[J].全面腐蚀控制, 2010, 1(3):22-24
[13]董黎明.冷凝式锅炉热平衡计算方式初探[J].工业锅炉, 2010, 1(04):15-16
[14]王哲 王景甫 郭莲莲.烧结矿等效导热系数实验测量及分析[J].过程工程学报, 2017, 17(4):879-882
[15]陈瑞芳, 丁道宁, 穆颖, 等.差示扫描量热法测定锌粉和富锌底漆中的锌含量[J].上海涂料, 2010, 48(9):43-45
[16]ASTM D6580-2000( 2009 ). 锌粉颜料及富锌漆干膜中金属锌含量测定的标准方法
[17]Davia L C, Artz B E.thermal conductivity of metal matrix composites[J].Journal of Applied Physics, 1995, 77(10):4954-4960
[18]贾思洋, 杨万国, 张波.涂层厚度对传热系数的影响研究[J].现代涂料与涂装, 2011, 14(1):25-27
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