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油酸辅助水热合成纳米钛酸锶的性能调控与表征

  • 张娜 钟莉 段东平
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  • 1. 中国科学院绿色过程与工程重点实验室,北京 100190 2. 中国科学院大学化学工程学院,北京 100049

收稿日期: 2019-01-24

  修回日期: 2019-04-15

  网络出版日期: 2019-12-22

基金资助

高纯氢氧化锶生产新工艺及产业化;基于含氟烟气净化的介孔氧化铝的可控合成基础研究

Regulation of properties and characterization of strontium titanate nanoparticles synthesis by oleic acid-assisted hydrothermal process

  • Na ZHANG Li ZHONG Dongping DUAN
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  • 1. Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China 2. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received date: 2019-01-24

  Revised date: 2019-04-15

  Online published: 2019-12-22

Supported by

;Fundamental Research on the Controllable Synthesis of Mesoporous Alumina for the Purification of Fluorine Flue Gas

摘要

采用油酸辅助一步水热法,以廉价易得的锐钛矿型TiO2为钛源、Sr(OH)2?8H2O为锶源合成SrTiO3纳米颗粒,通过XRD, TEM和SEM研究了SrTiO3纳米颗粒的形貌,考察了反应时间、Sr/Ti摩尔比和油酸浓度对SrTiO3纳米颗粒性能的影响,以所制SrTiO3为催化剂降解亚甲基蓝考察其光催化性能。结果表明,钙钛矿型立方相SrTiO3纳米颗粒具有均匀的尺寸和规则的形貌。实验范围内,随反应时间和Sr/Ti摩尔比增加,SrTiO3纳米粒子的晶粒尺寸呈增加趋势;随油酸浓度增加,SrTiO3颗粒粒度呈下降趋势。添加油酸可调控制备出具有规则形貌的钙钛矿型立方相结构的SrTiO3纳米颗粒;Sr/Ti摩尔比为0.75时,产品纯度高、结晶度好。油酸、反应时间和Sr/Ti摩尔比对SrTiO3纳米粒子微观结构的影响可分别用颗粒间作用力、奥斯特瓦尔德熟化和晶体成核理论解释。

本文引用格式

张娜 钟莉 段东平 . 油酸辅助水热合成纳米钛酸锶的性能调控与表征[J]. 过程工程学报, 2019 , 19(6) : 1212 -1219 . DOI: 10.12034/j.issn.1009-606X.219122

Abstract

Due to its excellent photocatalytic activity and piezoelectricity properties, SrTiO3 has attracted much attention in environmental photocatalysis, electronic and ceramic industries. SrTiO3 nanoparticles were synthesized by one-step oleic acid-assisted hydrothermal process using anatase TiO2 and Sr(OH)2?8H2O in this work. SrTiO3 nanoparticles were analyzed. The effects of oleic acid concentration, reaction time and Sr/Ti molar ratio on the properties of SrTiO3 nanoparticles were researched, photocatalytic property of the prepared SrTiO3 catalyst was investigated by the degradation of methylene blue. The results showed that perovskite phase cubic SrTiO3 nanoparticles with uniform size and regular morphology. The grain size of SrTiO3 nanoparticles increased with the increase of reaction time and Sr/Ti molar ratio, while decreased with the increase of oleic acid concentration. The agglomerate phenomenon of SrTiO3 nanoparticles became weaken and perovskite phase cubic SrTiO3 nanoparticles with regular morphology were obtained with the addition of oleic acid. When the Sr/Ti molar ratio was 0.75, the purity of the product was high. The influence of oleic acid concentration, reaction time and Sr/Ti molar ratio on microstructures of SrTiO3 nanoparticles could be explained by interparticle force, Ostwald ripening and crystal nucleation theory, respectively.

参考文献

[1]Ohtomo A, Hwang H Y.A high-mobility electron gas at the LaAlO3SrTiO3 heterointerface[J].Nature, 2004, 427(6973):423-426 [2]Kato H, Kudo A.Visible-light-response and photocatalytic activities of TiO2 and SrTiO3 photocatalysts codoped with antimony and chromium[J].Journal of Physical Chemistry, 2002, 106(19):5029-5034 [3]Konta R, Ishii T, Kato H.Photocatalytic activities of noble metal ion doped SrTiO3 under visible light irradiation[J].Journal of Physicals Chemistry B, 2004, 108(26):8992-8995 [4]Kholkin A, Bdikin I, Ostapchuk T.Room temperature surface piezoelectricity in SrTiO3 ceramics via piezoresponse force microscopy[J].Applied Physics Letters, 2008, 93(22):222905- [5]Haeni J H, Irvin P, Chang W.Room-temperature ferroelectricity in strained SrTiO3[J].Nature, 2004, 430(7001):758-761 [6]Szot K, Speier W, Bihlmayer G.Switching the electrical resistance of individual dislocations in single-crystalline SrTiO3[J].Nature Materials, 2006, 5(4):312-320 [7]Wang Z, Cao M, Yao Z.Giant permittivity and low dielectric loss of SrTiO3 ceramics sintered in nitrogen atomosphere[J].Journal of the European Ceramic Society, 2014, 34(7):1755-1760 [8]Lu Z, Zheng H, Lei W.High-Figure-of-Merit thermoelectric La-doped a-site-deficient SrTiO3 ceramics[J].Chemistry of Materials, 2016, 28(3):925-935 [9]Cardona M.Optical properties and band structure of SrTiO3 and BaTiO3[J].Physical Review B, 1965, 140(2A):651-655 [10]Wang J S, Yin S, Komatsu M, et al.Preparation and characterization of nitrogen doped SrTiO3 photocatalyst[J].Journal of Photochemistry and Photobiology A: Chemistry, 2004, 165(1-3):149-156 [11]Townsend T K, Browning N D, Osterloh F E.Nanoscale strontium titanate photocatalysts for overall water splitting[J].ACS Nano, 2012, 6(8):7420-7426 [12]Domen K, Kudo A, Onishi T.Mechanism of photocatalytic decomposition of water into H2 and O2 over NiO-SrTiO3[J].Journal of Catalysis, 1987, 18(3):92-98 [13]Ohno T, Tsubota T, Nakamura Y, et al.Preparation of S,C cation-codoped SrTiO3 and its photocatalytic activity under visible light[J].Applied Catalysis A:General, 2005, 288(1):74-79 [14]Puangpetch T, Sreethawong T, Yoshikawa S, et al.Synthesis and photocatalytic activity in methyl orange degradation of mesoporous-assembled SrTiO3 nanocrystals prepared by sol–gel method with the aid of structure-directing surfactant[J].Journal of Molecular Catalysis A: Chemical, 2008, 287(1):70-79 [15]Li X, Zhao H L, Shen W, et al.Synthesis and properties of Y-doped SrTiO3 as an anode material for SOFCs[J].Journal of Power Sources, 2007, 166(1):47-52 [16]陈贞亮, 王政存.溶胶-凝胶法制备纳米钛酸锶[J].功能材料, 1999, 30(6):633-635 [17]Chen Z L, Wang Z C.Preparation of strontium titanate nanoparticles by sol-gel method[J].Journal of Functional Materials, 1999, 30(6):633-635 [18]Kumar V.Solution-precipitation of fine powders of barium titanate and strontium titanate[J].Journal of the American Ceramic Society, 2010, 82(10):2580-2584 [19]Wang N, Kong D, He H.Solvothermal synthesis of strontium titanate nanocrystallines from metatitanic acid and photocatalytic activities[J].Powder Technology, 2011, 207(1-3):470-473 [20]Zhang Y B, Zhong L, Duan D P.A single-step direct hydrothermal synthesis of SrTiO3 nanoparticles from crystalline P25 TiO2 powder[J].Journal of Materials Science, 2016, 51(2):1142-1152 [21]Wang J S, Yin S, Zhang Q W, et al.Hydrothermal synthesis of strontium titanate powders with nanometer size derived from different precursors[J].Journal of the European Ceramic Society, 2000, 20(9):1261-1265 [22]Chen D, Jiao X, Zhang M.Hydrothermal synthesis of strontium titanate powders with nanometer size derived from different precursors[J].Journal of the European Ceramic Society, 2000, 20(9):1261-1265 [23] Kimijima T, Kanie K, Nakaya M, et al.Solvothermal synthesis of SrTiO3 nanoparticles precisely controlled in surface crystal planes and their photocatalytic activity [J]. [J].Applied Catalysis B: Environmental, 2014, 144:462-467 [24]Wei X, Xu G, Ren Z H, et al.PVA-assisted hydrothermal synthesis of SrTiO3 nanoparticles with enhanced photocatalytic activity for degradation of RhB[J].Journal of the American Ceramic Society, 2010, 91(11):3795-3799 [25]Zhang S, Liu J, Han Y, et al.Formation mechanisms of SrTiO3 nanoparticles under hydrothermal conditions[J].Materials Science and Engineering: B, 2004, 110(1):11-17 [26] Scherrer P.Bestimmung der Gr?sse und der inneren Stukturt von Kolloidteilchen mittels R?ntgenstrablen [J].[J].G?ttinger Nachrichten Gesell, 1918, 2:98-100 [27]Patterson A L.The Scherrer formula for X-ray particle size determination[J].Physics Review, 1939, 56(15):978-982 [28]李洁,王勇,韩艳芳,等.氢氧化钠熔盐分解钛渣制备二氧化钛的热力学分析[J].化工学报, 2012, 63(6):1669-1677 [29]Li J, Wang Y, Han Y F, et al.Thermodynamic analysis of titanium dioxide prepared by decomposition of titanium slag by sodium hydroxide molten salt[J].Journal of Chemical Industry and Engineering, 2012, 63(6):1669-1677 [30]Watanabe M.The investigation of sodium titanates by the hydrothermal reactions of TiO2 with NaOH[J].Journal of Solid State Chemistry, 1981, 36(1):91-96 [31]Christenson H K.DLVO (Derjaguin–Landau–Verwey–Overbeek) theory and solvation forces between mica surfaces in polar and hydrogen-bonding liquids[J].Journal of the Chemical Society, 1984, 7(80):1933-1946 [32]Vanoss C J, Giese R F, Costanzo P M.Dlvo and non-dlvo interactions in hectorite[J].Clays and Clay Minerals, 1990, 38(2):151-159 [33] Fujinami K, Katagiri K, Kamiya J, et al.Sub-10 nm strontium titanate nanocubes highly dispersed in non-polar organic solvents [J].[J].Nanoscale, 2010, 2:2080-2083 [34]Voorhees P W.The theory of ostwald riping[J].Journal of Statistical Physics, 1985, 38(1-2):231-252 [35] Zhan H Q, Jiang X P, Li X H, et al.Formation mechanisms of monodisperse strontium titanate nanocrystalline [J].[J].Chinese Journal of Inorganic Chemistry, 2015, 31(5):888-894
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