单分散纳米银胶体的快速制备及其在H2O2检测中的应用

丁梦玲	丁赔赔	张天宇	赵真田	孙乐乐	冒爱琴

doi:10.12034/j.issn.1009-606X.215274

过程工程学报 >

2015 , Vol. 15 >Issue 5: 866 - 870

DOI: https://doi.org/10.12034/j.issn.1009-606X.215274

材料工程专栏

单分散纳米银胶体的快速制备及其在H2O2检测中的应用

丁梦玲丁赔赔张天宇赵真田孙乐乐冒爱琴

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安徽工业大学材料科学与工程学院安徽工业大学材料科学与工程学院安徽工业大学材料科学与工程学院安徽工业大学材料科学与工程学院安徽工业大学材料科学与工程学院安徽工业大学材料科学与工程学院

收稿日期: 2015-07-20

修回日期: 2015-08-17

网络出版日期: 2015-10-20

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Quick Synthesis of Water-dispersed Ag Nanoparticles and Their Application in Detection of H2O2

DING Meng-ling DING Pei-pei ZHANG Tian-yu ZHAO Zhen-tian SUN Le-le MAO Ai-qin

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School of Materials Science and Engineering, Anhui University of Technology School of Materials Science and Engineering, Anhui University of Technology School of Materials Science and Engineering, Anhui University of Technology School of Materials Science and Engineering, Anhui University of Technology School of Materials Science and Engineering, Anhui University of Technology School of Materials Science and Engineering, Anhui University of Technology

Received date: 2015-07-20

Revised date: 2015-08-17

Online published: 2015-10-20

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摘要

以葡萄糖(C6H12O6)为还原剂、聚乙烯吡咯烷酮(PVP)为分散剂，采用液相还原法在室温水体系中快速制备不同浓度的纳米银粒子，对产物进行了表征，并将其用于H2O2检测. 结果表明，通过控制NaOH和PVP用量，可制得粒径30~55 nm、纯相的球形纳米银胶体，在H2O2检测中活性良好. 纳米银胶体表面等离子共振峰强度变化与H2O2浓度呈线性关系，H2O2的检测灵敏度高，检测限为5.0′10-7~5.0′10-2 mol/L.

关键词： 纳米银; 室温; 水分散; 双氧水; 检测

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丁梦玲丁赔赔张天宇赵真田孙乐乐冒爱琴 . 单分散纳米银胶体的快速制备及其在H2O2检测中的应用[J]. 过程工程学报, 2015 , 15(5) : 866 -870 . DOI: 10.12034/j.issn.1009-606X.215274

Abstract

Water-dispersed silver nanoparticles (AgNPs) were quickly synthesized with glucose (C6H12O6) as reducing agent and polyvinyl pyrrolidone (PVP) as surfactant at room temperature by liquid reduction method, and characterized. The results show that the spherical-shaped and phase-pure crystalline nano AgNPs with the diameters of 30~55 nm can be obtained by adjusting the concentrations of NaOH solution and PVP. And the colloidal silver nanoparticles exhibit an activity in the reduction of hydrogen peroxide (H2O2). The change in the absorbance strength of surface plasmon resonance is linear with the concentration of H2O2. Good sensitivity and linear response over the wide concentration range of 5.0′10-7~5.0′10-2 mol/L H2O2 are established.

Key words： silver nanoparticles; room temperature; aqueous dispersion; hydrogen peroxide; detection

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